As RJ mentioned, that's a parallel flash memory chip. To program it, you need 22 signals. The Pickit only has 2 or 3.
You would either need to find a parallel eprom or flash reader or would need to wire up a micro (PIC, AVR, or the like) to it and write a program that would read and write the flash. Not too difficult to do, but not plug-and-play.
/mike