I suspect that while removing the opto sockit, one of the traces going to pin 1 or pin 2 got broke. I would remove the sockit again and replace it.
1. Remove sockit.
2. Clean off all solder with a sucker, or desoldering wick.
3. Then using some fine sandpaper, remove the solder mask to expose clean shinny copper traces, All 4 top and bottom".
4. Then before inserting the new socket, bend out pins 1, 4, 6.
5. Insert socket and bend out pins 2, 3.
6. Now solder pins 2, 3, 5 on bottom of board, ensuring good solder flow.
7. Flip the board and solder pins 1, 4, 6 on top of board, ensuring good solder flow.
My cheepo camera will not give me a helpfull picture. But, I think you get the idea.
1. Channel 4 starts out at the 3.3v supply, hooked up to pin 1 of all the optos.
2. From pin 2 of the opto to the + side of the green led.
3. From the - side of the green led to pin 5 of the pic chip, and pin 5 of the ICSP.
If this all checks out good I would consider the led suspect, Not often, but it does happen.
Hope this helps